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天然产物对照品之硫代葡萄糖苷类物质种类和结构（四）
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资讯中心
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来源：
2019/08/15 16:35
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硫代葡萄糖苷（Glucosinolate, GSL, 简称硫苷，也称芥子油苷）是植物中一种重要的次生代谢物质，在十字花科植物中广泛存在，通常情况下以钾盐或钠盐的形式存在于细胞质中，不仅具有多种生物活性，还是十字花科蔬菜风味和气味形成的重要的前体物质。硫代葡萄糖苷由β-D-葡萄糖、磺酸肟和氨基酸的侧链R组成，根据侧链R的不同，GSL在结构上可分为脂肪族硫苷、芳香族硫苷和吲哚族硫苷，三类代表性单体硫苷化学的结构式，如图1 所示：
硫代葡萄糖苷种类比较丰富, 目前己鉴定的有200多种，其中多糖基硫苷、含硒硫苷及其它硫苷种类和结构，如下表和图2所示：
|
编号 |
中文名称 |
化学名称 |
中/英文俗名 |
|
149 |
2-(α-L- 鼠李糖基氧基)苄基硫苷 |
2-(α-L-Rhamnopyranosyloxy)benzyl glucosinolate |
|
|
150 |
4-(α-L-鼠李糖基氧基)苄基硫苷 |
4-(α-L-Rhamnopyranosyloxy)benzyl glucosinolate |
|
|
151 |
4-(4'-O-乙酰基α-L-鼠李糖基氧基)苄基硫苷 |
4-(4'-O-Acetyl-α-L-Rhamnopyranosyloxy)benzyl glucosinolate |
|
|
152 |
4-(4'-H-3'-O-乙酰基-α-L-鼠李糖基氧基)苄基硫苷 |
4-(4'-H-3'-O-Acetyl-α-L-Rhamnopyranosyloxy)benzyl glucosinolate |
|
|
153 |
4-(4'-乙酰基-α-L-鼠李糖基氧基)苄基硫苷 |
4-(4'-O-Acetyl-α-L-Rhamnopyranosyloxy)benzyl glucosinolate |
|
|
154 |
3-羟基-4-(α-L-鼠李糖基氧基)苄基硫苷 |
3-Hydroxy-4-(α-L-Rhamnopyranosyloxy)benzyl glucosinolate |
|
|
155 |
2-(α-L- 阿拉伯吡喃糖基氧基)-2-苯基乙基硫苷 |
2-(α-L-Arabinopyranosyloxy)-2-phenylethyl glucosinolate |
|
|
156 |
3-O-阿糖基葡糖基木质素硫苷 |
4-Hydroxy-3-apiofuranosyloxybenzyl glucosinolate |
Glucohesmatrolalin |
|
157 |
4-羟基-3-(2'-O-3,4-二羟基苯甲酰基阿拉伯糖基氧基)苯甲基硫苷 |
4-Hydroxy-3-[2’-(3,4-dihydroxybenzoyl)apiofuranosyloxy]benzyl glucosinolate |
|
|
158 |
4-羟基-3-(2'-O-4-羟基-3-甲氧基苯甲酰基阿拉伯糖基氧基)苯甲基硫苷 |
4-Hydroxy-3-[2’-(4-hydroxy-3-methoxybenzoyl)apiofuranosyloxy]benzyl glucosinolate |
|
|
159 |
4-羟基-3-(2'-O-3-羟基-4-甲氧基苯甲酰基阿拉伯糖基氧基)苯甲基硫苷 |
4-Hydroxy-3-[2’-(3-hydroxy-4-methoxybenzoyl)apiofuranosyloxy]benzyl glucosinolate |
|
|
160 |
3-O-乙基肉桂基葡糖醛酸3,4-二甲氧基苯甲酰酯硫苷 |
4-Hydroxy-3-[2’-(3,4-dimethoxybenzoyl)apiofuranosyloxy]benzyl glucosinolate |
|
|
161 |
4-甲硫基丁基-6'-苯甲酰基硫苷 |
4-Methylsulfanybutyl-6'-benzoyl glucosinolate |
|
|
162 |
4-甲基亚硫酰基丁基-6'-苯甲酰基硫苷 |
4-Methylsulfinylbutyl-6'-benzoyl glucosinolate |
|
|
163 |
4,6'-二苯甲酰基硫苷 |
4,6'-Dibenzoyl glucosinolate |
|
|
164 |
烯丙基硒代葡萄糖苷 |
2-Propenylselenoglucosinolate |
Selenosinigrin |
|
165 |
3-丁烯基硒代葡萄糖苷 |
3-Butenylselenoglucosinolate |
Glucoselenonapin |
|
166 |
4-(甲基亚磺酰基)-3-丁烯基硫苷 |
4-Methylsulfinyl-3-Butenyl glucosinolate |
Glucoraphenin |
|
167 |
4-甲基亚磺酰基-3-丁烯基-6-芥子酰-β-D-1-硫苷 |
4-Methylsulfinyl-3-Butenyl-6-Sinapoyl-β-D-1-glucosinolate |
|
|
168 |
4-甲基亚硫酰基-3-丁烯基-2'-O-芥子酰硫苷 |
4-Methylsulfinyl-3-Butenyl-2'-O-Sinapoyl glucosinolate |
|
|
169 |
4-甲基亚硫酰基-3-丁烯基-2',6'-O-二芥子酰硫苷 |
4-Methylsulfinyl-3-Butenyl-2',6'-O-Disinapoyl glucosinolate |
|
|
170 |
4-甲基亚硫酰基-3-丁烯基-6'-O-肉桂酰硫苷 |
4-Methylsulfinyl-3-Butenyl-6'-O-Cinnamoyl glucosinolate |
|
|
171 |
3-(甲基亚硫酰基)丙基硫苷 |
3-Methylsulphinylpropyl glucosinolate |
Glucoiberin |
|
172 |
3-甲基亚硫酰基丙基-6’-O-芥子酰硫苷 |
3-Methylsulphinylpropyl-6'-O-Sinapoyl glucosinolate |
|
|
173 |
2(S)-羟基-2-苯基乙基硫苷 |
2(S)-Hydroxy-2-phenylethyl glucosinolate |
|
|
174 |
2-苯基-2-羟基乙基-6'-O-肉桂酰硫苷 |
2-Phenyl-2-Hydroxyethyl-6'-O-Cinnamoyl glucosinolate |
|
|
175 |
2-苯基-2-羟基乙基-6'-O-异阿魏酰硫苷 |
2-Phenyl-2-Hydroxyethyl-6'-O-Isoferuloyl glucosinolate |
|
|
176 |
2-苯基-2-羟基乙基-2'-O-异阿魏酰硫苷 |
2-Phenyl-2-Hydroxyethyl-2'-O-Isoferuloyl glucosinolate |
|
|
177 |
2-苯基-2-羟基乙基-2',6'-O-二异阿魏酰硫苷 |
2-Phenyl-2-Hydroxyethyl-2',6'-O-Diisoferuloyl glucosinolate |
|
|
178 |
2-对羟基苯基-2-羟基乙基硫苷 |
(2S)-2-Hydroxy-2-(4-hydroxyphenyl)ethyl glucosinolate |
|
|
179 |
2-对羟基苯基-2-羟基乙基-6'-O-异阿魏酰硫苷 |
6'-isoferuloyl-(S)-2-hydroxyphenyl-2-phenylethyl glucosinolate |
|
|
180 |
2-对羟基苯基-2-羟基乙基-2'-O-异阿魏酰硫苷 |
2'-isoferuloyl-(S)-2-hydroxyphenyl-2-phenylethyl glucosinolate |
|
|
181 |
2-对羟基苯基-2-羟基乙基-2',6'-O-二异阿魏酰硫苷 |
2',6'-Diisoferuloyl-(S)-2-hydroxyphenyl-2-phenylethyl glucosinolate |
|
|
182 |
肉桂酰硫苷；苯丙烯酰硫苷 |
Cinnamoyl glucosinolate |
|
|
183 |
邻-香豆酰硫苷 |
O-Coumaroyl glucosinolate |
|
|
184 |
间-香豆酰硫苷 |
m-Coumaroyl glucosinolate |
|
|
185 |
对香豆酰硫苷 |
p-Coumaroyl glucosinolate |
|
|
186 |
咖啡酰硫苷；二羟基桂皮酰硫苷 |
Caffeoyl glucosinolate |
|
|
187 |
阿魏酰硫苷 |
Feruloyl glucosinolate |
|
|
188 |
异阿魏酰硫苷 |
Isoferuloyl glucosinolate |
|
|
189 |
芥子酰硫苷 |
Sinapoyl glucosinolate |
|
|
190 |
3-(甲硒基)丙基硫苷 |
3-(Methylseleno)propyl glucosinolate |
Glucoselenoiberverin |
|
191 |
4-(甲硒基)丁基硫苷 |
4-(Methylseleno)butyl glucosinolate |
Glucoselenoerucin |
|
192 |
5-(甲硒基)戊基硫苷 |
5-(Methylseleno)pentyl glucosinolate |
Glucoselenoberteroin |
|
193 |
2-甲硒基-4-羟基-吲哚-3-甲基硫苷 |
Methylselenohydroxy glucobrassicin |
|
|
194 |
2-甲硒基-4-甲氧基吲哚-3-甲基-4-甲氧基硫苷 |
Methylseleno-4-methoxyglucobrassicin |
|
|
195 |
2-甲硒基-1-甲氧基吲哚-3-甲基硫苷 |
2-Methylseleno-N-Methoxyindol-3-ylmethylglucosinolate |
|
图2 含硫侧链硫代葡萄糖苷结构
经过多年积累，华士特生物专业开发不同种类硫代葡萄糖苷类（芥子油苷类）对照品/标准品等产品，产品数量不断更新，可提供5mg~25mg等常规包装和100mg以上的大规格包装，并开展硫代葡萄糖苷（芥子油苷）检测分析，满足客户的不同需求，详情请咨询客服人员，如有天然产物对照品和检测需求，以及寻求相关生物资源深度开发与利用技术的合作意向，欢迎咨询洽谈！
关键词：
硫代葡萄糖苷对照品
芥子油苷对照品
硫代葡萄糖苷检测
芥子油苷检测
硫代葡萄糖苷标准品
芥子油苷标准品
硫苷对照品
硫苷标准品